Electrochemistry

Learning outcomes - after studying this topic, you should be able to:
  • Identify oxidation and reduction half-reactions, and combine them into a balanced redox reaction
  • explain how a Galvanic cell is constructed to draw a current from a redox reaction
  • use the activity series to decide which element or compound is the stronger oxidant
  • calculate the (standard) cell potential and determine the spontaneous direction of a redox reaction under standard conditions
  • calculate the cell potential for standard and non-standard conditions from the half-cell reactions, and determine the spontaneous direction of a redox reaction
  • calculate equilibrium constants from standard cell potentials and vice versa
  • combine reaction quotient and cell potential information to solve for unknown concentrations both at equilibrium and away from equilibrium
  • identify the key design features of an electrochemical sensor, and calculate an unknown concentration for appropriate electrochemical data

Textbook and eBook References

ChemCAL, iChem and Contributed Resources

Electrochemistry
Contributed by Adam Bridgeman
 
 
Complexes and redox equations
Contributed by Adam Bridgeman
 
 
Electrochemistry
Contributed by Adam Bridgeman
 
 
Balancing redox equations
Tags: redox equations
Contributed by Adam Bridgeman
 
 
Cell potentials
Tags: Galvanic cells | voltaic cells
Contributed by Adam Bridgeman
 
 
Galvani cells
Tags: Galvanic cells | voltaic cells
Contributed by Adam Bridgeman
 
 
Redox Reactions and Cell Potentials
Tags: redox | cell potentials | half cells
Contributed by Adam Bridgeman
 
 
Electrochemical Cells (short video tutorial)
Tags: Galvanic | voltaic | electrolytic
Contributed by Adam Bridgeman