Ionisation Constants of Acids in Water Solution at 298 K

Formula

pKa

 

Formula

pKa

H2SO3

1.90

 

H2S

7.02

HSO4-

1.99

 

H2PO4-

7.20

H3PO4

2.13

 

HSO3-

7.20

CH2ClCOOH

2.86

 

HOCl

7.54

HNO2

3.14

 

N2H5+

7.94

HF

3.17

 

HCN

9.22

HCOOH

3.74

 

H3BO3

9.24

CH3CHOHCOOH

3.86

 

NH4+

9.24

C6H6COOH

4.20

 

C6H5OH

9.98

C6H5NH3+

4.61

 

HCO3-

10.33

CH3COOH

4.76

 

CH3CH2NH3+

10.67

CH3CH2 CH2COOH

4.82

 

HPO42-

12.36

CH3CH2COOH

4.87

 

HS-

12.89

NH3OH+

5.96

 

CH3CH2OH

>15.7

H2CO3

6.35

 

H2O

15.7

 

Common Acid-Base Indicators

Indicator Name

Colour Change

(low to high pH)

pKa

methyl yellow

red – yellow

3.1

methyl orange

red – yellow

3.7

methyl red

pink – yellow

5.1

bromothymol blue

yellow – blue

7.0

cresol red

yellow – red

8.3

phenolphthalein

colourless – red

9.6

alizarin yellow

yellow lilac

11.1