The learning outcomes for this unit are described below. These outcomes are built from the learning activities in lectures, tutorials, laboratory and independent study. Important attributes are:
- the ability to apply scientific knowledge and critical thinking to identify, define and analyse problem and create solutions: you will be expected to demonstrate these outcomes on problems drawn from the material presented in the course and to novel situations.
- the ability to evaluate your own performance and development and to recognize gaps in your knowledge: keep a portfolio of your progress using the 'self assessment tool'
- Generic Attributes
By the end of this topic, you should be able to
- apply scientific knowledge and critical thinking to identify, define and analyse problems, create solutions, evaluate opinions, innovate and improve current practices
- gather, evaluate and deploy information relevant to a scientific problem
- disseminate new knowledge and engage in debate about scientific issues
- recognize the rapid and sometimes major changes in scientific knowledge and technology, and to value the importance of continual growth in knowledge and skills
- use a range of computer software packages in the process of gathering, processing and disseminating scientific knowledge
- make value judgements about the reliability and relevance of information in a scientific context
- evaluate your own performance and development, to recognize gaps in knowledge and acquire new knowledge independently
- set achievable and realistic goals and monitor and evaluate progress towards these goals
- appreciate sustainability and the impact of science within the broader economic, environmental and socio-cultural context
- present and interpret data or other scientific information using graphs, tables, figures and symbols
- work independently and as part of a team and to take individual responsibility with a group for developing and achieving goals
- actively seek, identify and create effective contacts with others in a professional and social context, and maintain those contacts for mutual benefit
- recognize the importance of safety and risk management and compliance with safety procedures
- manipulative equations and measurements with due regard for significant figures and unit conventions
- Laboratory Skills
By the end of this topic, you should be able to
- perform careful and safe experiments
- accurately report scientific observations
- work as a professional scientist with due regard for personal safety and for the safety of those around you
- interpret observations in terms of chemical models with appropriate use of chemical equations and calculations
- perform calculations containing concentrations, moles and masses
- choose and use appropriate glassware for a given task
- choose and use balances accurately and appropriately
- present and interpret data or other scientific information using graphs, tables, figures and symbols
- work as a member of a team and to take individual responsibility within a group for developing and achieving group goals
- actively seek, identify and create effective contacts with others in a professional and social context, and maintain those contacts for mutual benefit
- Elements and Atoms
By the end of this topic, you should be able to
- explain what an element is
- appreciate that elements may be metals or non-metals and may be solids, liquids or gases and what these terms mean
- recognize that elements are labelled using their chemical symbol
- explain the differences between elements, compounds and mixtures
- explain the difference between allotropes and the physical state of an element
- explain what atoms are and how they combine to form compounds
- appreciate the difference between physical and chemical properties
- list the particles that make up atoms, their symbols and their relative masses and charges
- read and write the atomic symbol containing the mass number and atomic number
- explain what isotopes are and work out the number of neutrons an isotope contains from its atomic symbol
- explain how elements can change into another by radioactive decay
- explain what light is and how its energy is related to its frequency and wavelength
- draw the shell structure of atoms with up to 18 electrons
- Molecules and Ions
By the end of this topic, you should be able to
- work out the number of electrons an ion has from its symbol
- recognize that most ions have a Noble gas configuration
- predict whether an element will form a cation or an anion
- explain the characteristics of ionic bonding
- read and write the chemical formula of ionic compounds
- name simple binary ionic compounds according to IUPAC nomenclature
- explain how covalent molecules are bonded together and how they differ from ionic compounds
- draw simple Lewis dot and line diagrams showing single, double and triple bonds and lone pairs
- read and write the chemical formula of covalent compounds
- use molecular formula, empirical formula and structural formula
- name simple covalent compounds using IUPAC nomenclature
- predict the polarity of the bonds in molecules
- list the properties of metallic, ionic and covalent solids
- Chemical Equations
By the end of this topic, you should be able to
- explain what chemical reactions are and why they occur
- identify reactions as being combination, precipitation, decomposition, replacement or acid/base
- write balanced chemical equations for reactions of neutral species, including physical states
- write balanced chemical equations for reactions involving charged species, including physical states
- write balanced ionic equations for reactions without spectator ions, including physical states
- list the characteristics of acids including their reactions
- Stoichiometry
By the end of this topic, you should be able to
- work out atomic mass as a weighted average of isotope masses
- work out the molecular mass of a covalent compound from its chemical formula
- work out the formula mass of an ionic compound from its chemical formula
- relate the mass of a substance to the number of particles it contains using Avogadro's constant
- appreciate what a mole of substance is
- convert between mass and moles and between moles and mass
- work out which reactant is the limiting reagent in a reaction and use it to predict how much product can form
- work out the percentage yield in a chemical reaction by identifying the limiting reagent and the theoretical yield
- use experimentally determined percentage composition to work out the empirical formula
- identify the solvent, solute and solution for a reaction in a solution
- interconvert between moles, concentration and volume given two of these quantities
- The Periodic Table
By the end of this topic, you should be able to
- recognize the relationships between elements in the same periods and in the same groups
- predict the properties of an element from its position, including its metallic, semi-metallic or non-metallic properties and the acid, basic or amphoteric properties of its oxide
- Lewis Model of Bonding
By the end of this topic, you should be able to
- draw Lewis structures for molecules containing single and multiple bonds and with lone pairs
- draw resonance structures for molecules where more than one Lewis structure is possible
- recognize that molecules with resonance structures have bonds which are intermediate between single and double bonds
- VSEPR
By the end of this topic, you should be able to
- work out the number of bonding and non-bonding pairs from the Lewis structure of a molecule
- predict the distribution of these pairs around an atom
- place any lone pairs in appropriate positions to minimize the overall electron pair repulsion
- predict and describe the molecular shape
- First Law of Thermodynamics
By the end of this topic, you should be able to
- explain the difference between heat and temperature
- identify a process as endothermic or exothermic from the temperature change
- relate temperature and heat change using specific and molar heat capacities
- calculate internal energy changes using the bomb calorimeter
- define the difference between internal energy and enthalpy
- obtain the enthalpy change using a coffee-cup calorimeter
- use Hess's Law
- estimate reaction enthalpies from bond energies
- define standard states
- combine enthalpies of formation to work out the enthalpy change for chemical reactions
- combine enthalpies of reactions to work out the enthalpies of formation
- explain the advantages and disadvantages of solid, petroleum, hypergolic and cryogenic (hydrogen) fuels
- work out the efficiency of fuels
- Types of Intermolecular Forces
By the end of this topic, you should be able to
- describe the different kinds of intermolecular forces that exist
- identify which intermolecular forces are present and which are more important between different molecules
- relate variations in melting and boiling points in related compounds to their intermolecular forces
- describe the subunits of synthetic and natural polymers
- outline the role of intramolecular and intermolecular forces on the primary, secondary, quaternary and tertiary structure of synthetic and natural polymers
- Chemical Equilibrium
By the end of this topic, you should be able to
- explain the dynamic nature of equilibrium processes
- write the equilibrium constant for any reaction or process
- use initial, change, equilibrium (ICE) tables and the small 'x' approach to work out equilibrium concentations
- use Le Chatelier's principle to predict the response of a system at equilibrium to changes in temperature, pressure and composition
- explain the difference between the equilibrium constant, K, and the reaction quotient, Q
- write down the reaction quotient and use it to predict the direction of change
- explain how catalysts effect chemical reactions without changing the equilibrium concentrations
- Equilibrium and Thermochemistry in Industrial Processes
By the end of this topic, you should be able to
- explain the main processes used industrially to extract metals from their ores
- use Ellingham diagrams to predict which metals can be extracted using coke at different temperatures
- outline the thermodynamic principles behind the industrially optimized routes to sulfuric acid and ammonia
- Electrochemistry
By the end of this topic, you should be able to
- relate the sign of the electrode potential to the direction of spontaneous change
- combine half cells to produce balanced redox reactions and to calculate cell potentials
- identify the species which are being oxidzied and those being reduced in a redox reaction
- write down the cell notation for a Galvanic cell including ones involving inert electrodes
- use the Nernst equation to calculate the effect of concentration on the cell potential
- relate the electrode potential and the reaction quotient
- relate the standard electrode potential and the equilibrium constant
- Electrolytic Cells
By the end of this topic, you should be able to
- identify the processes and species formed at the anode and cathode of Galvanic and electrolytic cells
- identify the direction of electron flow in Galvanic and electrolytic cells
- identify what can be electroysed and the role of over-potential in the electrolysis of water and in the production of NaOH and Cl2
- use Faraday's Laws of Electrolysis to relate the amount of product to the electric current applied