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CHEM1109 - Resources for Week 11






Week 10

Topics and learning outcomes

 

  • Chemical Kinetics
    •  determine the rate law from experimental data, including the rate constant and its units
    •  identify the reaction order from the rate law
    •  use the integrated rate law and half life for 1st order reactions
    •  recognize the effect of temperature on reaction rates and be able to use the Arrhenius equation in calculations
    •  recognize that chemical reactions result from multistep processes called reaction mechanisms
    •  recognize the role of activation energy and collision frequency in determining rates
    •  work out a rate law from a simple proposed mechanism
    •  draw reaction profile diagrams for multi-step reactions with appropriate activation energies and intermediates
    •  calculate Ea and A from the temperature variation of the rate constant
    •  know how catalysts effect the rate of reactions without altering equilibrium constants
    •  explain the Michaelis-Menton mechanism of enzyme catalysis
    •  use the steady-state approximation to derive the rate law for a multi-step reaction involving a reactive intermediate

Textbook references

 
  • Chemical Kinetics - Chapter 14
 
references are to Blackman, Bottle, Schmid, Mocerino and Wille, Chemistry, 2nd Edition, 2012 (John Wiley)

Lecture notes, tutorial homework and resources


ChemCAL and other resources

 
Chemical Kinetics
To access ChemCAL, use the username "1109" and the password "helium"

Contributed links

You can contribute resources to this site and rank the existing resources: log in to eLearning and follow the link to 'Contribute' under 'Course Resources'.

Chemical Kinetics -


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Week 12


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