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Functional Groups


A functional group is a group of atoms that has a characteristic chemical behaviour. An organic molecule can be viewed as an inert skeleton of C–C single bonds saturated with H's with functional groups attached at different positions. It is the functional groups that determine the types of reactions that the molecule will undergo. Functional groups are as basic to organic chemistry as words are to language or chords are to music. When you take an organic course, they need to be learnt and committed to memory as soon as possible - understanding organic chemistry is impossible if this is not done. To help you to memorize them, try out the:
Functional Group Flashcards
There are many functional groups, some very common, others less so. The table below lists some common function groups. The structures have been drawn as stick structures - roll the mouse over the molecule to reveal the full structural representation. For help on drawing stick structures, see the pages on organic structures and stick structures and formulae.


Functional Group


Structural Features


Example

alkene

carbon-carbon double bond

arene (aromatic ring)

conjugated double bonds in a flat ring

primary amine

NH2 group attached to a carbon chain

secondary amine

NH2 group attached to two carbon chains

primary alcohol

OH group attached to a carbon chain

phenol

OH group attached directly to an aromatic ring

ether

2 carbon chains attached to the same oxygen atom

aldehyde

CHO group attached to a carbon chain

ketone

C=O group attached to two carbon chains

carboxylic acid

COOH group attached to a carbon chain

ester

COO group attached to 2 carbon chains
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